Synthesis of very long chain fatty acid methyl esters
نویسندگان
چکیده
منابع مشابه
Crystallization Behavior of Fatty Acid Methyl Esters
Biodiesel from most agricultural feedstocks has flow properties that are prone to startup and operability problems during cold weather. Biodiesel from soybean oil is generally a mixture of long-chain fatty acid alkyl esters composed of 0.15–0.20 mass fraction saturated esters (melting point [MP] 0 C) mixed with unsaturated esters (MP \ 0 C). This work investigates the crystallization properties...
متن کاملSynthesis of long-chain fatty acid enol esters isolated from an environmental DNA clone.
[structure: see text] Long-chain fatty acid enol ester 1 is the major metabolite of a new family of small molecules isolated from the heterologous expression of environmentally derived DNA. A versatile synthesis of 1, in which an aromatic acetaldehyde is O-acylated with a long-chain acyl chloride allowed for the rapid construction of both the isolated product (1) and a number of structural anal...
متن کاملChloroacetamide Mode of Action, II: Inhibition of Very Long Chain Fatty Acid Synthesis in Higher Plants
In short-term-experiments [14C]-labelled malonic acid, stearic acid and acetate have been incorporated into leaf fatty acids of seedlings of Cucumis sativus, Hordeum vulgare and Zea mays. The pattern of labelled fatty acids changed markedly by treatment with the chloroacetamide herbicides metazachlor, metolachlor or butachlor. During a 2-h incubation time, 1 μm chloroacetamide specifically inhi...
متن کاملPlasmalogens participate in very-long-chain fatty acid-induced pathology.
Peroxisomes are organelles responsible for multiple metabolic pathways including, the biosynthesis of plasmalogens, a class of phospholipids, and the beta-oxidation of very-long-chain fatty acids (VLCFA). Lack of peroxisomes or dysfunction in any of their normal functions is the cellular basis for human peroxisomal disorders. Here we used mouse models to understand and define the biochemical an...
متن کاملChloroacetamide Mode of Action, I: Inhibition of Very Long Chain Fatty Acid Synthesis in Scenedesmus acutus
H erbicidal chloroacetam ides cause a very sensitive inhibition of fatty acid incorporation into an insoluble cell wall fraction of Scenedesm us acutus. The m olecular basis was investi gated in m ore detail. A fter incubation of the algae with [14C]oleic acid and saponification, the rem aining pellet was solubilized and fractionated consecutively with chloroform /m ethanol, phosphate buffer, ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Chemical Society, Perkin Transactions 1
سال: 1993
ISSN: 0300-922X,1364-5463
DOI: 10.1039/p19930001183